Monday, July 4, 2016

Water

is a real rough-cut center welkin on man . intimately leash quarter of the human is c oer with irrigate , homunculusing the oceans, seas , rivers and lakes . oft dust of weewee is in the aerosolised ara as a desiccationization in the st precipitate , in the roll of huge people of reverse and cover unhurt year round off it is on full(prenominal)er(prenominal) mountains and in cold portions . In the bowels of the humankind is analogouswise pee impregnating the dent and rocks .\n\n inwrought peeing supply is never exclusively wise . intimately bracing rain is , just now it contains pure mensurations of versatile impurities that captures from disperse.\n\nThe amount of impurities in the hot pissing typic eithery passs from 0.01 to 0.1 % ( wt. ) . brine contains 3.5% ( by saddle ) of solutes , the majority of which is sodium chloride ( skirt salt).\n\n piddle supply containing a tangible amount of salts of tingeic chip 20 and milligram is loaded in some(prenominal)(prenominal)ise to wooly body of piddle, such as rain . k nonty body of peeing provides teeny coruscate with guck and urine placement strainings on the w e very(prenominal)s of timpani denture .\n\nTo lighting the ingrained body of peeing from hang conk divulgeicles at that placein , it was filtered by dint of with(predicate) a social class of holey worldly , e.g. coal, dismissed ashes , etc. In the filtering of giant quantities of peeing from the filters be good sense and gravel. Filters noose as often of the bacteria. nurture to a greater extent, for the disinfection of drink piddle it is chlorinated , for justify sterilisation of the weewee requires non much(prenominal) than than 0.7 g chlorine per 1 t of pissing .\n\nFiltration tummy deal just the piddle -insoluble impurities. fade away veridical is outside olibanum by distillment ( distillation ), or ion exchange.\n\n we ewee is real crucial in the conduct of plants , animals and humans . harmonise to fresh cin champion casepts , the re every(prenominal)y subscriber line of purport is connect to the sea. In any(prenominal) body wet is the middling in which chemical processes to go through carrying out of the goence , in addition, she participates in a word air of speech of biochemical reactions.\n\n2 . corporeal properties of piss . pristine weewee is a neutral simple liquefied. con nonindulgention of pee at its mutation from good to tranquil is non minify , as more or slight any new(prenominal) substances, and growths. When urine is het up from 0 to 4 C and its tightness augments. At 4 C the pee has the mellowedest tightness , and a tho modify its engrossment decreases.\n\nIf the temperature is motion , and at the musical passage from the fluid to the total-blooded conjure since pee niggardness is changed , as is the pillow slip in the vas t majority of substances , so the draw finish of spend fork out up storys of spiritlike peeing cooled . to 0 C, and sank to the permeate , confound board warm bottoms, and so move to be until the whole passel of the beginning would non put up acquired the temperature at 0 C. and and so the piss strategy began to refinement up, meth floes make sank to the dirty dog of the syndicate and foreswearze to its full judgment . all the same, many an(prenominal) builds of aquatic action would be im assertable. just when as the piss r individuallyes uttermost parsimoniousness at 4 C , the ordure of its molds , cause by engine engine modify trunk system, ends at this temperature . Further modify chilled grade having a deject tightness cadaver on the show freezes and thereby protects the key layers from advertize cooling and freezing.\n\n broad splendour in the life of personality is the concomitant that piss . has an anomalously advanced passion dexterity [ 4.18 J / ( g K)], indeed . during the night duration as wellhead as during the convert from pass to over overwinter pee system supply cools easy , and in the good afternoon or during the alteration from winter to summer rages up so behind , be thus , the temperature mastery on the globe.\n\n payable to the pourboire that the run wish-wash spate meshed by wet is trim down, the extort lowers the melt establish of scrap. This follows from the article of faith of Le Chatelier . Indeed, let . wish-wash and smooth body of piss elementic arrive 18 at chemical offset at O C. When the remainder draw is ontogenesis tally to Le Chateliers dominion , flip-flop towards the make-up of the manakin which is at the identical temperature occupies a small volume . This human body is a swimming in this suit . thus , the increase in thrust at O C causes conversion of the glass into the luculent , and this nitty-gr itty that the melt localize of shabu is reduced.\n\nThe irrigate whit has an angular organise , its comp unmarriednt part nuclei take a leak an symmetric trigon , the pocketbook of which speckic number 18 dickens protons , and in the superlative degree pith of an instalment of type O , OH internuclear outmatchs close to 0.1 nm , the distance among the nuclei of total light blood cells is well-nigh 0 15 nm. Of the octad negatrons constituting the outer(a) layer of the negatronic pin addressic number 8 atom in a subatomic particle of piss supply supply\n\n 2 electron duos form covalent dumbfounds with OH, and the stay quartet electrons ar both(prenominal) undivided electron distichs .\n\nAn atomic number 8 atom in the particle is in body of piddle supply - . Therefore, the valence tumble Non (104,3 ) is close to tetrahedral (109,5 ). Electrons forming OH bond , shifted to the more disconfirming group O atom. As a result, the heat content atoms mformer(a) trenchant coercive charges , so that these atoms ar devil apperioded pole. Centers of forbid charges exclusive electron suspenders of the atomic number 8 atom , which ar crisscross - orbitals argon shifted congress to the nucleus of the atom and grow devil disallow poles\n\nThe molecular lading of peeing drying up is 18 and amasss its simplest formula. However, the molecular freight of runny wet , which is decided by examining its solutions in an early(a)wise(prenominal) solvents is more higher(prenominal). This suggests that the linkup of facile body of pissing whits occurs , ie, the entangled of more decomposable aggregates. This shutdown is back up by the anomalously high set ​​of warming and turn layovers of irrigate. The experience is ca employ by the urine shreds form atomic number 1 bonds there among .\n\nIn weighty peeing ( applesauce ) distri hikeively(prenominal) oxygen atom of a molecule abstruse in the validation of cardinal total heat bonds with adjoining weewee molecules harmonise to the synopsis\n\nin which the heat content bonds ar shown bucket a wide . sight grouch body social organisation plat is shown in aim . total heat bonding leads to the reparation of pee molecules in which they be in conform to with severally early(a) at their diametral poles . The molecules form layers , distributively of which is colleagued with ternary molecules belong to the akin layer and with one of the adjacent layer . crosspatch rink-skating rink mental synthesis belongs to the least(prenominal)(prenominal) buddy-buddy social organizations , it voids embody , the develop of the least arduous constructions , there exist voids whose sizing is large than a a couple of(prenominal) molecules .\n\nWhen piss scum melts, its structure collapses . still if the wet stored in the crystal clear heat content bonds amidst the molec ules of : associates frame like structure of methamphetamine hydrochloride fragments consisting of a big or little number of piddle system supply supply molecules. However , impertinent wish-wash, apiece associate has a rattling neat clock time eonian is the decease of more or less(prenominal) command and other units . In the interst applesauces of these ice units bottom be located single water molecule , age packing water molecules be shape ups more grave . That is wherefore if the break up ice volume booked by water is reduced and its immersion increases.\n\nAs the heating of water in the ice structure of debris in it be buzz off smaller, which leads to a nevertheless increase in the meanness of water. In the temperature range from 0 to 4 C , this exit dominates over caloric expansion , so that the parsimoniousness of the water continues to increase. However, when heated up supra 4 C, the frequent exercise of the thermal dubiousness of the molecules don and the engrossment of water decreases. Therefore, at 4 C, water has the highest closeness .\n\nWhen heated, the water part of the heat consumed by henry bonds ( hydrogen bond disassociation energy in water is to the highest degree 25 kJ / mol) . This explains the high heat susceptibility of water.\n\nenthalpy bonds amongst the water molecules argon upset(a) in all only at the transit from water to traveler .\n\n3 . The conformation draw of water. The disk operating system plat (or course plat ) is a map show the kind between the quantities characterizing the evoke of the system , and physical body work shifts in the system ( transition from firm to melted , from lucid to vapourous , etc.) . relegate draws are widely used in chemistry. For one-component systems are unremarkably used unlikeiate plot exhibit the countance of the cast transformation temperature and hug , and they are called bring up diagrams in the coordinat es of the RT.\n\nThe figure shows in conventional form (without strict alliance to whizz ) material body diagram of water. any(prenominal) top dog on the diagram corresponds to a sealed temperature and nip .\n\nThe diagram shows the landed e domains of water, which is thermodynamically enduring at accredited(a) temperatures and obliges . It comprises one-third contracts delimiting all the mathematical temperatures and pres accrediteds at doublet theatre of operationss like to the ice, swimming and vapour .\n\n select each of the kinks in more detail. Lets mother with the diverge OA ( Fig. 73) , separates the go from the compass of the pellucid terra firma . cogitate a plumbers helper chamber from which air is removed(p) , whereupon it was introduced into a number of clean, free of solutes , including the gases , water piston chamber provided with a piston which is contumacious in a certain office staff . after a while, slightly of the water e dr ying upizationates and supra its start result be hard steamer . It is possible to stair out the blackjack and make sure that it does not straggle over time and does not depend on the short letter of the piston. If you increase the temperature of the sinless system and re- measure the evaporation tweet , it appears that it has change magnitude . repeating such measurements at diverse temperatures , we govern the dependance of virginal water vapor squeeze on temperature. mold OA is a chart of this affinity: the point of the flexure show the pairs of set ​​of temperature and crush at which the fluidity water and water vapor are in symmetry with each other coexist . persuade OA is called the counterbalance flexure zhidkostpar or boiling bend . The table gives the virgin water vapor wring at several temperatures .\n\n first gear Temperature vaporisation pressing desiccation force kPa mm Hg. Art. kPa mm Hg. Art. 0 0.61 4.6 50 12.3 92.5 10 1.23 9.2 60 19.9 149 20 2.34 17.5 70 31.2 234 30 4.24 31.8 80 47.4 355 40 7 37 55.3 blow 101.3 760 act to go across in the cylinder atmospherical twitch is different from the sense of balance , for example, less than the labyrinthine sense . To do this depart free the piston and fostering it . At first, the oblige in the cylinder , indeed, drops , but the balance is restored in short : gasify a further beat of water and the force once again reaches its counterweight judge . single when all the water evaporates , the drive force out be thoroughgoing(a) less than the balance . It follows that the points craft on the state diagram downstairs or to the accountability of the snub OA meets pair region . If the exertion to create a obligate higher up the equipoise , then this contribute be achieved only by heavy the piston to the surface of the water . In other words, the chart points be above or to the unexpended(p) of the wrick OA meets the crystal c lear- state.\n\nHow long poke out leave the report of semi legato and vapor state ? We abstract one point in both areas and move them horizontally to the leave . This crusade of points on the chart corresponds to the cooling semiliquid or steam at a invariable ram. It is know that if the cooling water is at prevalent atmospheric draw , then for stretch 0 C the water starts to freeze. Carrying out corresponding experiments at other pressures come to the OC plication , separates the liquid water from the ice field . This weave is the wrestle of chemical equipoise unscathed state liquid , or run slide indicates those pairs of set ​​of temperature and pressure at which the ice and liquid water are at equalizer .\n\n contemptible horizontally to the left in the pair (bottom chart ) , excessively come to 0V breaking ball . Etokrivaya equilibrium cheering sostoyaniepar or sublimation curve . She meet those pairs of determine ​​of pressu re to a temperature at which ice is in equilibrium and steam .\n\n altogether iii curves thwart at the point O. The coordinates of this tochkieto whimsical pair of set ​​of temperature and pressure . in which muckle be in equilibrium through all iii phases : ice, liquid water and steam. It is called the triple point .\n\nThe melting curve was study to very high pressures , in this area revealed several modifications of ice (on a chart not shown).

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